Pearson baccalaureate chemistry higher level 2nd edition print and online edition for the ib. For a continuous probability distribution function pdf x, the proba bility, p. The corresponding uncertainties are u r, u a, u b, and u c. As a special case of this, if you add a quantity with an uncertainty to an exact number, the uncertainty in the sum is just equal to the uncertainty in the original uncertain quantity. The uncertainty of a calculation is always greater than the individual. Therefore, the ability to properly combine uncertainties from different measurements is crucial.
Multiplication or division of data means that the percentage uncertainties must be added. For example, during a titration there are generally four separate pieces of apparatus, each of which contributes to the uncertainty. Ib chemistry on uncertainty, error analysis, random and. Ib chemistry, uncertainty, error analysis, standard deviation. Your ib physics course book to help you gauge your progress and understanding, the answers for all the material in your ib physics course book are available here. Measurement uncertainty distributions and uncertainty propagation by the simulation. A situation that is often encountered in chemistry is the use of a calibration curve to determine a value of some quantity from another, measured quantity. Although the claim may be true in some cases, marlap rejects this argument as an excuse for failing to perform a full evaluation of the measurement uncertainty. Depaul university, chemistry department, 1036 west belden avenue, chicago, il 606143214 cite this. Whenever experiments are carried out involving more than one step, the uncertainties of each step must accumulate. For example, in chem 120 you created and used a calibration curve to determine the percent by mass of aluminum in alum. Step 1 the mass of solid needed for preparation of the solution is weighed out and then recorded mass of potassium hydrogen phthalate 1.
Be sure to calculate a percent uncertainty and an absolute. Quantifying uncertainty in analytical measurement citac. When the estimate of an input quantity is taken from an external source, such as a book or a cali. In that exercise, we did not propagate the uncertainty associated with. Ib chemistry, ib biology on uncertainty calculation, error.
You must show the propagation of uncertainties here. For the equations in this section we represent the result with the symbol r, and the measurements with the symbols a, b, and c. Ib chemistry investigations teaching notes shoppe pro. A propagation of uncertainty allows us to estimate the uncertainty in a result from the uncertainties in the measurements used to calculate that result.
A propagation of uncertainty allows us to estimate the uncertainty in a result from the uncertainties in the measurements used to calculate the result. The international union of pure and applied chemistry iupac defines a. Pearson baccalaureate download ebook pdf, epub, tuebl, mobi. If you add or subtract data then the uncertainties must also be added. A catalog record tor this book is available from the library of congress. Department of analytical chemistry, permoserstrasse.
For the equations in this section we represent the result with the symbol r, and we represent the measurements with the symbols a, b, and c. Download pearson baccalaureate or read online books in pdf, epub, tuebl, and mobi format. Horwitz w 2000 official methods of analysis of aoac international. Ib chemistry, ib biology on uncertainty calculation, error analysis a. A note on covariance in propagation of uncertainty. In analytical chemistry, there has been great emphasis on the precision of results obtained using a specified. When using multiplication, division or powers then percentage uncertainties should be used during the calculation and then converted back into an absolute uncertainty when the final result is presented. Click download or read online button to get pearson baccalaureate book now. Chemistry iupac, and the international organization for standardization.